Academic Resources Core-content Links

  • Home
  • LINKS (Under Construction)
    • Business>
      • Accounting & Finance
        • Economics
        • Natural Sciences>
          • Chemistry
            • Biology & Nutrition
              • Environmental Science, Ecology, & Conservation
                • Anatomy & Physiology
                  • Geology, Geography, & GIS
                  • Mathematics>
                    • Algebra / Trigonometry, Precalculus, Plane Geometry
                      • Calculus & Differential Equations
                        • College Algebra, Pre-calculus (w/o Trig), Foundations of Math, Finite Math
                        • Humanities & Foreign Language>
                          • Art & Music
                            • French
                            • Engineering>
                              • Computer Engineering
                                • AutoCad
                                  • Automotive Technology
                                    • Chemical Engineering
                                      • Architecture & Civil Engineering
                                        • Computer Engineering
                                          • Electrical & Biomedical Engineering (including Electronics)
                                          • Computers>
                                            • Computer Science
                                              • Computer Software
                                                • C / C++ Programming
                                                  • Assembly Language Programming & Microprocessors
                                                    • Database Programming (incl. Oracle & SQL)
                                                      • Email Accounts & Internet Searches
                                                      • Careers & Online Learning>
                                                        • Careers & Job Search
                                                        • English & Writing>
                                                          • English Composition & Writing
                                                            • ESL
                                                            • Social Sciences
                                                              • Study Skills & Testing
                                                                • Miscellaneous Academic References
                                                                  • Calculators
                                                                  • Tutor's Blog
                                                                   
                                                                  General Chemistry: Electron Domain Geometry versus Molecular Geometry 04/27/2011
                                                                  2 Comments
                                                                   
                                                                        A molecule can have a different shape when  referring to its electron-domain geometry than when referring to its molecular geometry.  For example, sulfur dioxide, SO2,  electron-domain geometry is trigonal planar. This is because it has 3 electron domains - the 6 valence electrons for sulfur form 2 single bonds with 2 oxygen atoms and sulfur has one non-bonding lone pair.  Also related to electron-domain geometry is the fact that the sulfur has sp2 hybridization, since its geometry is trigonal planar.
                                                                      When referring to the molecular geometry for sulfur dioxide, the molecular geometry is bent.  Note that the bent shape is related to the diffence in electronegativity between sulfur and oxygen (3.5 - 2.5). Since the difference in polarity is greater than zero, SO2 is a polar molecule.  The polarity influences  the bond angle for the bent geometry. The lone pairs are not considered when determining molecular geometry, only the bonds with the atoms are considered.
                                                                  If the central atom of a molecule has no lone pairs, the molecular geometry and the electron-domain geometry are the same.  For example, carbon tetrachloride, CCl4, has no lone pairs on the central carbon atom.  Its molecular geometry and its electron-domain geometry is tetrahedral.
                                                                  2 Comments
                                                                   
                                                                  First Post! 04/23/2011
                                                                  0 Comments
                                                                   
                                                                  Start blogging by creating a new post. You can edit or delete me by clicking under the comments. You can also customize your sidebar by dragging in elements from the top bar.
                                                                  Add Comment
                                                                   

                                                                    Author

                                                                    K. Foster
                                                                    Laboratory Technician
                                                                    Academic Support Center
                                                                    Southwest TN Community College
                                                                    I tutor courses in Math, Physics, and Chemistry.

                                                                    Archives

                                                                    April 2011

                                                                    Categories

                                                                    All
                                                                    Chemistry; Shape Of Molecules

                                                                    RSS Feed


                                                                  Create a free website with Weebly